Product ID:PRESTONE GIANT SPRAY DE-ICER, AS244
MSDS Date:01/24/1991
FSC:6850
NIIN:00N056399
MSDS Number: CDMCX

FIRST BRANDS CORP

83 WOOSTER HTS RD BLDG 301
DANBURY, CT 06813-1911
US

Emergency Phone: 800-424-9300 (CHEMTREC)

Info Phone: 203-731-2300

Cage: DO273

PRESTONE PRODUCTS CORP

DANBURY, CT 06810-5109 US

Telephone: 203-731-3686/830-7865

Cage: 0CXZ7

ETHYLENE GLYCOL (SARA 313) (CERCLA)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 5-9%

OSHA PEL N/K

ACGIH TLV: C 50 PPM, VAPOR

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 70-80%

OSHA PEL S, 200 PPM

ACGIH TLV: S, 200 PPM/250 STEL

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1,2-PROPANEDIOL; (PROPYLENE GLYCOL)

CAS: 57-55-6

RTECS: TY2000000

Fraction By Weight: 5-9%

OSHA PEL N/K

ACGIH TLV: N/K

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

Fraction By Weight: 1-5%

OSHA PEL 5000 PPM

ACGIH TLV: 5000 PPM/30000 STEL

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 5-9%

OSHA PEL N/K

ACGIH TLV: N/K

FOLLOWS SWALLOWING OF LG VOLUMES OF ETHYLENE GLYCOL.

RTECS: 9999999ZZ

PRLNGD & WIDESPREAD CONT MAY RSLT IN ABSORP OF

RTECS: 9999999ZZ

DROW, DISTURB OF VISION, & TINGLING, NUMBNESS &

RTECS: 9999999ZZ

CAUSE IRRIT OF NOSE & THROAT W/HDCH, PARTICULARLY

RTECS: 9999999ZZ

PRLNGD CONT TO

RTECS: 9999999ZZ

DISCOMFORT W/MILD REDNESS & SWELL OF CONJ & POSS

RTECS: 9999999ZZ

TERM RPTD OVEREXP TO METHANOL VAP CONCS OF 3000

RTECS: 9999999ZZ

NAUS, VOMIT, HDCH, RINGING IN EARS, INSOMNIA,

RTECS: 9999999ZZ

LIVER &/OR KIDNEY INJURY MAY OCCUR. PRLNGD OVEREXP @

RTECS: 9999999ZZ

SOME PEOPLE. RPTD SKIN CONT MAY CAUSE SENSIT

RTECS: 9999999ZZ

GLYCOL @ HIGH DOSES IS TO BE REGARDED AS ANIMAL

RTECS: 9999999ZZ

EMER MED FACILITY. TAKE PATIENT & CNTNR TO

RTECS: 9999999ZZ

IMMED WASH EXPOS AREAS W/SOAP & COPIOUS AMTS OF

RTECS: 9999999ZZ

FLUSH W/COPIOUS AMTS OF CLEAN WATER,

RTECS: 9999999ZZ

SWELL/TEARING PERSIST, SEEK MED ATTN. FOR MORE INFO

RTECS: 9999999ZZ

EXHAUST MAY BE NEEDED TO MAINTAIN EXPOSURE LEVELS

RTECS: 9999999ZZ

29 CFR 1910.134 & GOOD INDUSTRIAL HYGIENE

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:CONTAINS METHANOL &
ETHYLENE GLYCOL. METHANOL MAY CAUSE NAUS, ABDOM PAIN, VOMIT,
SHORTNESS OF BREATH, FATG & LEG CRAMPS. NERV SYS EFTS INCL:HDCH,
CONFUSN, DRUNKEN BEHAVIOR, CNS DEPRESS, C OMA & DEATH. VISUAL EFTS
FROM METHANOL INCL BLURRED VISION, DOUBLE VISION, CHANGES IN COLOR
PERCEPTION,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:RESTRICTION OF VISUAL FIELDS &
COMPLETE BLNDNESS. W/MASSIVE OVERDOSES, LIVER, KIDNEY & HEART
MUSCLE INJURY HAVE BEEN DESCRIBED. THERE MAY BE DELAY OF SEVERAL
HRS BETWEEN SWALLOWING METHANOL & ONSET OF SIGNS & SYMPS. INGEST
OF MOD QTYS OF METHANOL ALSO PRDCES METABOLIC ACIDOSIS. ONSET OF
SYMPS MAY BE (SUPDAT)
Medical Cond Aggravated by Exposure:DUE TO ITS DEFAT PROPERTIES,
METHANOL MAY AGGRAVATE EXISTING SKIN CNDTN, E.G., ECZEMA. DUE TO
ITS LIVER & KIDNEY INJURING POTNTL, PROD MAY EXACERBATE EXISTING
LIVER AND/OR KIDNEY DISEASES.

First Aid:INGEST:GIVE 2 GLASSES OF WATER & INDUCE VOMIT IMMED. NEVER
GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET MED HELP URGENTLY BY
CALLING PHYS, EMER ROOM/POIS CTL CTR. ETHANOL (WHISKEY, BRANDY,
ETC.) IS EFT IVE ANTIDOTE. MED PERS MAY INSTRUCT YOUTO ADMIN
ETHANOL TO PATIENT DEPENDING ON NUMBER OF VARIABLES SUCH AS AMT OF
PROD SWALLOWED, TIME ELAPSED SINCE INGEST & TIME NEEDED TO GET
PATIENT TO (ING 17)

Flash Point Method:PMCC
Flash Point:58F,14C
Extinguishing Media:FOAM, ALCOHOL FOAM, CARBON DIOXIDE OR DRY CHEMICAL
FOR SMALL FIRE. WATER FOG FOR LARGE FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . AEROSOL FLAME EXTENTION:>18 IN. LEVEL 2 AEROSOL.
Unusual Fire/Explosion Hazard:DO NOT INCINERATE AEROSOL CONTAINER/STORE
CONTAINER IN AREA >120F(49C). CANS OF PACKAGED PRODUCT MAY RUPTURE
IF EXPOSED TO HEAT.

Spill Release Procedures:WEAR APPROP PERSONAL PROTECTIVE EQUIPMENT &
REMOVE ALL SOURCES OF IGNITION. COLLECT MATERIAL FOR DISPOSAL IN
CONTAINER SUITABLE FOR FLAMMABLE WASTE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DANGER:FLAMM. MAY BE FATAL/CAUSE
BLNDNESS IF SWALLOWED. DO NOT SWALLOW. DO NOT BREATHE VAP. USE ONLY
W/ADEQ VENT. AVOID CONT W/EYES, SKIN & CLOTHING.
Other Precautions:KEEP AWAY FROM SOURCES OF HEAT, SPARKS, FLAME & OUT
OF DIRECT SUNLIGHT. DO NOT EXPOSE TO TEMPERATURES >120F. OBSERVE
ALL REQUIREMENTS OF PLANT, COMPANY/GOVT REGS. KEEP OUT OF REACH OF
CHILDREN.

Respiratory Protection:OPERATIONS WHERE TLV MAY BE EXCEEDED, NIOSH
APPRVD SUPPLIED AIR RESP IS REC. ODOR IS NOT RELIABLE INDICATOR OF
OVEREXP, SO NIOSH APPRVD AIR-PURIFYING EQUIP IS NOT REC. EQUIP
SELECTION DEPENDS ON CONTA M TYPE & CONC, SELECT I/A/W (ING 22)
Ventilation:GEN VENT SHOULD BE ADEQ FOR NORM USE. FOR OPERATIONS WHERE
TLV MAY BE EXCEEDED, FORCED VENT SUCH AS LOCAL (ING 21)
Protective Gloves:CHEM RESIST, SUCH AS NITRILE/BUTYL RUBB.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . PROT
CLTHG IF NEEDED TO AVOID PRLNGD/RPTD SKIN CONTACT.
Work Hygienic Practices:CONTAMD CLTHG SHOULD BE REMOVED & LAUNDERED
BEFORE RE-USE. WASH EXPOSED SKIN W/SOAP AND WATER.
Supplemental Safety and Health
FL PT:58.0F,14.4C. METH:PMCC. EFTS OF OVEREXP:DELAYED UP TO 48HRS.
60-200 ML IS FATAL DOSE FOR MOST ADULTS. INGEST OF AS LITTLE AS 10
ML MAY CAUSE BLNDNESS. ETHYLENE GLYCOL, IN ADDN TO SHARING MANY OF
GI & NERV SYS EFTS OF METHANOL, ALSO CAUSES METABOLIC ACIDOSIS. IN
ADDN, SEV KIDNEY DMG & POSS KIDNEY FAILURE (ING 6)

Boiling Pt:B.P. Text:158F,70C
Melt/Freeze Pt:M.P/F.P Text:>-100F,>-73
Vapor Pres:47 @ 68F
Vapor Density:>1
Spec Gravity:0.857
Evaporation Rate & Reference:6 (BUTYL ACETATE =1)
Solubility in Water:100% BY WGT
Appearance and Odor:CLEAR COLORLESS LIQUID, ALCOHOL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
NORMALLY NONE.
Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAMES.
Hazardous Decomposition Products:BURNING MAY PRODUCE CO OR CO*2.

Waste Disposal Methods:WASTE MATERIAL IS RCRA HAZARDOUS WASTE DUE TO
IGNITABILITY. INCINERATION OR LANDFILLING SHOULD BE CARRIED OUT
I/A/W APPLICABLE RCRA FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.